09 March 2011, 05:15
farbedoThe Basics of Steel
To start this off, I feel that a short dissertation on steel and steel testing is in order. Some of you, no doubt, are familiar with this, but I would like to cover as much of the interested audience as possible. Please bear with me. I don't wish to come off preachy, etc. I just want to get the information out there so everyone is on the same page.
Steel Basics:
What is steel? Steel is the solid mixture of elemental iron and elemental carbon. Without carbon, you don’t have steel, and you don’t get all of the engineering possibilities that steel has. Carbon is the foundation for all alloying strategies. The carbon content dictates the achievable strength (this is a Key Concept). Low carbon, low strength, high carbon, high strength. From the the base of iron and carbon, we mix and match different alloys to meet a need. We also mix and match different processing to meet a need.
A Few Definitions and Explanations:
Alloy – any element that is mixed into the steel to enhance or change the behavior or properties of the steel. Carbon (most important element), manganese, nickel, chrome, vanadium, titanium, silicon, phosphorous, sulfur, nitrogen, niobium, tungsten, cobalt, and molybdenum are commonly used. Each alloy imparts some characteristic that the engineer wishes to harness.
Hardenability - This term describes how easy a steel is to heat treat. It is usually used in an abstract sense. Like "this steel has high hardenability". There are equations that directly compare one alloy to another. Generally speaking, the more alloy you add the higher the hardenability. This term also tells you if a steel will reach full hardness at depth as well as at the surface. If you have a 1 inch thick bar of low hardenability steel, only the surface or near surface will harden. The same size bar of high hardenability steel will harden all the way through. The thickness of the part is critical in choosing the alloy if the part is to be heat treated.
Hardness – A measure of the steels resistance to indentation. An indenter is forced into the surface of the steel part and the depth of the indentation is measured. Obviously, a soft steel will indent deeply compared to a hard steel. Hardness can be used to approximate the tensile strength of a material. It is also a good comparative test. There are several hardness tests out there. Rockwell, Knoop, Vickers, and Brinnell are the most common. Rockwell has several scales used, and needs to be carefully chosen based on the material being tested. The other 3 use one scale, and are adequate for most any material.
Keep in mind that a hardness test indents the surface of the material. This plays a part in the information the test gives you. Rockwell C is the common scale used in heat treating. This test measures both the surface and the core because it is designed to indent deeply. It can give you all of the information that you need, but you should understand it. This test will give you the same reading under different circumstances. If the case layer of a case hardened part is thin, but very hard, it will yield the same Rockwell C value as a a part with a case layer that is thicker, but softer. It gives you a composite value. A better method is to check with the Rockwell C test, then check on the Rockwell D scale as well. The D scale was intended for use on case hardened materials. It uses the same indenter as the C scale with a lower load. This means that it measures the case more than the base metal, and gives you more information about the case hardness. The combination can give you the case hardness, and maybe some information of the case depth. However, the only way to positively determine case depth is destructive testing.
That said, both situations would likely be safe in a firearm receiver. The purpose of the case hardened layer is only partially to hold the pressure back. It is this layer coupled with the size of the lug and the strength of the steel beneath the case that hold back the pressure. There is a caveat to this. The case layer should be thick enough to be durable over time, but it cannot be too hard. If it is too hard it will crack, or chip under impact.
Yield Strength – the force is takes to permanently deform a material. Usually denoted as pounds per square inch, or megapascals.
Tensile Strength – the force it takes to tear a material apart. Usually denoted as pounds per square inch, or megapascals. If this is exceeded, the receiver will be torn to pieces. Simple as that.
Elongation – How far a material stretches before is breaks. Denoted as a percentage.
Steel will yield at the yield strength, elongate some amount, then fracture at the tensile strength. This is what happens when receiver lugs set back. The force on the lugs has exceeded the yield strength and they are deformed. In case hardened receivers, the core material has a large gap between the yield and tensile strength. For a 1030 steel, the yield will be around 60,000 psi, and the tensile will be around 80,000 psi. It will have an elongation of something around 20%. This is good, because the receiver will tell you when you have gone too far without it turning into a grenade. The lugs set back, the bolt sticks, and you should stop shooting.
In an alloy steel receiver that is fully heat treated, the yield will be much closer to the tensile strength, but they will both be very high. For 4130, the yield will be something like 145,000 psi, and the tensile will be something like 150,000 psi. With and elongation of only 5%. In this case, the lugs would not set back, they would probably just shear off. However, it would take an impossibly overloaded cartridge to do it since the strength of the steel is so high. Maybe a 30-06 full of Blue Dot?
This is why the bottom receiver lug in a Ruger or Savage is half the size of the lug in a military Mauser. Ruger and Savage use alloy steels that are fully heat treated and rely on the strength from heat treating. The Mauser design relies of the size of the lug.
Toughness – This described how a material behaves under impact loading. A low toughness material shatters under impact, where a high toughness material takes the impact without deformation. Glass is an example of a low toughness material. A steel ball peen hammer head is an example of a high toughness material. This is a critical property. As quenched steel parts have low toughness, and must be tempered. More on this later.
Different Steel Classes:
Plain Carbon Steel – This is your basic steel made with limited alloying. These are typically alloyed with carbon, manganese, silicon, phosphorous, sulfur, and/or very small amounts of niobium, titanium, and vanadium. This group is also referred to as carbon/manganese steel. Carbon steel is divided into three groups: low carbon, medium carbon, and high carbon. Low carbon contains less than 0.25% carbon. Medium sits in the 0.25% to 0.40% carbon range. High carbon contains 0.40% up to 2.00% carbon. Once you add more than 2% carbon it is called Cast Iron, and this material is a completely different animal not suitable for much in a firearm.
Alloy Steel – Carbon steel has limitations in its application, so other alloy elements are added to enhance it. The most common of these steels will contain some combination of manganese, nickel, chrome, molybdenum, and vanadium. The most common that I have seen in the firearms industry are 4130, 4140, 4340, and 8620. There are many other alloy steels that are proprietary to a manufacturer. I have seen this with barrel makers.
The alloys added to this group are there for 2 primary reasons: increase hardenability, and inprove wear resistance. Nickel, manganese, molybdenum, vanadium, and chrome all increase hardenability. Adding these alloys allows the part to achieve full hardness all the way through on thicker and thicker sections. The other aspect is wear resistance. Chrome is the main alloy to improve wear resistance. It creates fine carbides within the steel that resist abrasion. Many knife makers use very high chrome alloys (52100 is common) to make them as wear resistant as possible. The same goes for ball bearings.
Stainless Steel – This group is alloyed primarily with chrome and nickel to achieve better corrosion resistance. The best corrosion resistance is achieved by adding 18% chrome and 8 % nickel. This makes 304 stainless used for things like kitchen sinks. However, adding too much chrome or nickel prevents the material from heat treating, so for firearms typically only chrome is used. The most common alloy is 440. There are 3 flavors of this alloy: 440A, 440B, and 440C. The difference is mainly in the carbon content. Nominally, A has 0.7% carbon, B has 0.9% carbon, and C has 1.10% carbon. So 440A won’t be as hard as, B or C, but it will be a tougher alloy. From a heat treating standpoint, these stainless alloys behave similarly to the Alloy Steels. Because only chrome is used, and because chrome forms carbides, 440 is not corrosion proof. It will rust, just not as fast as plain carbon steel, or alloy steel.
Steel Alloy Designations:
Steels have a standard system of alloy designations for commercially available alloys. This makes it easy for buyers to get the same steel from multiple sources.
The designation is broken down as follows: first two digits denote the alloy family, and the third and fourth digits denote carbon content in tenths of a percent.
So a 1040 steel is in the 10 family (plain carbon, or carbon manganese), has no additional special alloy additions, and contains 0.40% carbon.
4340 steel is in the 43 alloy family so it contains molybdenum, chrome and nickel. The last two digits say that it has nominally 0.40% carbon.
Stainless is designated a little differently, and the name only denotes which alloy family it is in. There is no information on carbon content. Common families for stainless are 300 and 400.
Design engineers will use alloys with whatever combination to achieve their desired end use. Large parts will have a lot of nickel and molybdenum in them. Wear resistant parts will have a lot of chrome in them. Corrosion resistant parts will have a lot of chrome and or a lot of nickel.
I hope that this is useful to you. The next installment will cover heat treating and carburizing.
Jeremy
10 March 2011, 01:42
farbedoLesBrooks, I find it odd and sad that they don't require a basic metallurgy course. I am sure that the instructor retired and they dropped it. Maybe the powers that be, figure the firearms manufacturers did the metallurgy for you. BUT, if you need to make a part, that no longer holds true.
I will also make sure to draw a hard line between pre WWII firearms, and post. With a distinction for military actions. You bring up a good point in that Mark X, and other flavors of post war Mauser clones need to be in a separate category.
Leo, That is also a good catch. I am trying to condense so much, and have missed a few details. Maybe at least I hit the high points.
Thanks for the feed back everyone.
Jeremy